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Melting Curves of Lower Mantle Phases

As silicate perovskite is widely believed to be the dominant phase of the Earth's lower mantle, the perovskite melting curve represents an upper bound to the temperature of this region, and places important constraints on the thermodynamic and rheological properties of the lower mantle. Again, experimental results reported over the last four years disagree. Sweeney and Heinz [1993] reported spatially averaged melt temperatures for perovskite between 30 and 94 GPa in a Nd:YAG laser-heated diamond cell. Their results support earlier studies which concluded that the melting temperature of perovskite is around 3000 K at 60 GPa, and the extrapolated melting temperature at the CMB pressure is 4500 500 K.

In contrast, Zerr and Boehler [1993] measured a melting temperature of 5000 200 K in their laser heating experiments at 62.5 GPa. Extrapolation to the CMB pressure yields a melting temperature between 7000 and 8500 K. A number of discussions of the relative merits of these experiments have been reported [ Heinz et al., 1991; Heinz et al., 1994; Boehler and Zerr, 1994]. The potential implications of a high melting temperature for perovskite on mantle dynamics have just begun to be addressed [ van Keken et al., 1994]. Extrapolation of recently measured melting curves (to 32 GPa) of MgO and (Mg,Fe)O indicates these materials melt at 3500-5000 K at lower mantle pressures [ Zerr and Boehler, 1994], but molecular dynamics calculations of MgO melting temperatures are higher by several thousand Kelvin [ Cohen and Gong, 1994]. The effect of minor components, including volatiles, on the melting behavior of lower mantle materials has not yet been studied.



U.S. National Report to IUGG, 1991-1994
Rev. Geophys. Vol. 33 Suppl., © 1995 American Geophysical Union