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The Sign of : A Question of Fluid Source?

Debates over directions of fluid flow in the presence of temperature gradients revolve around implications for contact metamorphic terranes. Studies of the Notch Peak contact-metamorphic aureole by Ferry and Dipple [1992] and Nabelek and Labotka [1993] focused the deliberations.

Ferry and Dipple [1992] proposed that HO-rich fluids that drove decarbonation reactions in the aureole flowed up temperature from low-grade rocks toward the igneous pluton that was the source of heat during metamorphism. Nabelek and Labotka [1993], building on their previous studies and those of their co-workers, presented evidence intended to controvert the model of Ferry and Dipple. They argued that the flow of aqueous fluid was down temperature away from the pluton.

Both proposed flow regimes are adequate to explain the major features of the aureole: a sequence of diopside and wollastonite isograds in calcareous argillites up temperature toward the pluton, and a general decrease in whole-rock argillite carbonate values toward the pluton. Although the distinction between the proposed models is usually cast in terms of direction of flow relative to temperature, the essence of the debate has as much to do with gradient versus fluid-driven reactions and, by corollary, the origin of the infiltrated fluid. Ferry and Dipple propose flow coupled with gradient reactions while Nabelek and Labotka propose flow coupled with fluid-driven reactions.

Ferry and Dipple based their model on the assumption that fluid entered the aureole in chemical and isotopic equilibrium with the distal country rock. The reactions that ensued were thus envisaged to have been gradient reactions. Reactant and product minerals are predicted to coexist over a distance prescribed by the rock alteration index , and consumption of reactant phases, comprising gradient reaction fronts, should not coincide with isograds if this model is correct (isograd is used here to refer to the first appearance of product minerals up temperature). Accordingly, Ferry and Dipple focused on field relations in the zones between the diopside and wollastonite isograds in which the relative positions of lines that apparently demarcate loss of reactant minerals (gradient fronts) relative to isograds serve to constrain their model. Flow up-temperature toward the pluton reproduces these relations. They interpreted the isotope data as being indicative of a gradual change in with distance as is expected for gradient isotopic exchange. Up-temperature flow was invoked to explain the decrease in argillite toward the pluton.

Nabelek and Labotka presented trace element evidence that indicate fluid that infiltrated the aureole came from the pluton and was not in equilibrium with the country rock. Fluid-rock reactions were therefore envisaged to be fluid-driven. Reactant and product minerals are not expected to coexist over finite distances because reaction progress is driven to completion by the difference in composition between infiltrated and equilibrated fluid. Isograds are thus fluid-driven reaction fronts in this model, and their positions are controlled by and the difference in composition between infiltrated and equilibrated fluid. Because fluid compositions at equilibrium are a function of temperature, the positions of the fronts envisaged by Nabelek and Labotka are a function of . In this circumstance the rock alteration index influences the positions of both gradient and fluid-driven fronts, although in different ways. Nabelek and Labotka interpreted the isotope data as defining a sharp step-like change in with distance, consistent with a fluid-driven exchange front.

The fundamental unknowns are the composition of the fluid relative to rock and the nature of the fluid-rock reaction. Derivation of reactive fluid from the pluton implies down-temperature flow, and derivation from distal country rock implies up-temperature flow assuming simple radial fluid stream lines, but there is little inherent in the direction of flow relative to itself that requires one model or the other. The salient features of the isotope data, for example, including the existence of a front like that described by Nabelek and Labotka, could be explained by up-temperature flow of a nonequilibrium fluid (instead of the down-T flow posited by the latter authors) if that fluid had values several per mil greater than indicated by equilibration with distal country rock [figure 2 of Dipple and Ferry, 1992]. One concludes that the oxygen isotope data can be explained by flow either up or down temperature given suitable initial for the infiltrated fluid. The most conspicuous mineralogical features of the aureole are also explained by either up or down-temperature flow, but only where the degree of equilibration between fluid and rock is specified expressly. For example, no one has suggested that fluid in equilibrium with the country rock flowed down temperature in the aureole because such a flow regime would have caused mineralogical reactions to progress in directions opposite to those observed [e.g., Dipple and Ferry, 1992; Ferry, 1991]. Down-temperature flow is permitted for fluid-driven reactions but gradient reactions coupled with down-temperature flow are precluded by first-order observations.

Both models for development of the Notch Peak aureole are based on continuum mechanics and were acknowledged by the protagonists to be at least partly schematic. In the future, the assumptions inherent in the continuum models can be tested at sub-REV scales. Such investigations should help sharpen our picture of aureole formation. Nabelek and Labotka alluded to this fact in their discussion of enhanced fracture flow in the wollastonite zone relative to the outer aureole.



next up previous
Next: Allochemical Metamorphism by Up: Fluid flow in metamorphic Previous: Isotope Tracers



U.S. National Report to IUGG, 1991-1994
Rev. Geophys. Vol. 33 Suppl., © 1995 American Geophysical Union